dc.contributor.author | Baygu, Yasemin | |
dc.contributor.author | Yıldız, Burak | |
dc.contributor.author | Karac, Izzet | |
dc.contributor.author | Dal, Hakan | |
dc.contributor.author | Gök, Yaşar | |
dc.date.accessioned | 2019-10-20T09:03:15Z | |
dc.date.available | 2019-10-20T09:03:15Z | |
dc.date.issued | 2018 | |
dc.identifier.issn | 1088-4246 | |
dc.identifier.issn | 1099-1409 | |
dc.identifier.uri | https://dx.doi.org/10.1142/S1088424618500104 | |
dc.identifier.uri | https://hdl.handle.net/11421/16665 | |
dc.description | WOS: 000427932100023 | en_US |
dc.description.abstract | New metalloporphyrazines (MgPz, ZnPz) containing peripheral tetrasubstitutions derived from 7,8-dihydro-6H, 14H, 19H-dibenzo[bj][1,12,5,8]-dioxadithiacyclopentadecine-16,17-dicarbonitrile (6) have been synthesized by a multistep reaction sequence and characterized. Compound 6 has been prepared by the reaction of 1,3-di(2-bromomethyl phenoxy) propane (3) or 1,3-di(2-iodomethylphenoxy) propane (4) which were prepared via bromination or iodination of {2-[3-(2-hydroxymethylphenoxy) propoxy]-phenyl} methanol (2) and cis-1,2-dicyano-1,2-ethylenedithiolate (5). The novel magnesium porphyrazine was prepared by the cyclotetramerization reaction of 6 with magnesium butoxide. The one-step synthesis of porphyrazinato zinc complex has been achieved without a reaction sequence by using dicyano compound (6) and zinc butoxide. The prediction of the geometry optimization, normal mode frequencies, H-1, C-13 NMR, UV absorption spectra, chemical shifts, electronic properties and NBO analysis of the compound were examined by using B3LYP method with a 6-31G(d, p) basis set. These novel compounds were characterized by a combination of elemental analysis, H-1, C-13 NMR, FT-IR, UV-vis and MS spectral data. An X-ray crystal structure of dicarbodinitrile compound (6) was also investigated. | en_US |
dc.language.iso | eng | en_US |
dc.publisher | World Sci Publ Co Inc | en_US |
dc.relation.isversionof | 10.1142/S1088424618500104 | en_US |
dc.rights | info:eu-repo/semantics/closedAccess | en_US |
dc.subject | Mixed-Donor Macrocycle | en_US |
dc.subject | Porphyrazine | en_US |
dc.subject | Template Reaction | en_US |
dc.subject | Green Chemistry | en_US |
dc.subject | X-Ray Investigation | en_US |
dc.subject | Computational Chemistry | en_US |
dc.title | Synthesis, characterization and computational investigation of novel metalloporphyrazines containing 15-membered O2S2-donor macrocyclic moieties | en_US |
dc.type | article | en_US |
dc.relation.journal | Journal of Porphyrins and Phthalocyanines | en_US |
dc.contributor.department | Anadolu Üniversitesi, Fen Fakültesi, Fizik Bölümü | en_US |
dc.identifier.volume | 22 | en_US |
dc.identifier.issue | 1.Mar | en_US |
dc.identifier.startpage | 207 | en_US |
dc.identifier.endpage | 220 | en_US |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
dc.contributor.institutionauthor | Dal, Hakan | |