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dc.contributor.authorKarakoç, Nimet
dc.date.accessioned2015-03-17T12:47:46Z
dc.date.available2015-03-17T12:47:46Z
dc.date.issued2004
dc.identifier.issn13023160
dc.identifier.urihttps://hdl.handle.net/11421/1709
dc.description.abstractIn this study, Schiff base (1) which was prepared from 2-hydroxy-1-naphtaldéhyde aniline and m-(methoxy) substituted aniline were reacted with DMSO, I₂,H₂S0₄ in the hope of preparing Schiff base which was substituted with iodine . The reaction has been carried out with DMS0-I₂-H₂S0₄ at 100°C under atmospheric conditions. Reaction has been followed with TLC and the pH of the reactions medium were approximately at 5. In the experiment was carried out approximately at pH ≡ 2 the azomethine (-CH=N-) bond breaking was found . The reaction of the naphtolic Schiff base (1) with DMSO-I₂-H₂S0₄ was carried out at 100°C for about 10 hours. The structure of product was determined by mass, IR, UV, ¹H-NMR, ¹³C-NMR spectra and with elemental analysis. Under our reaction condition iodine was substituted to the phenyl ring of the naphtolic Schiff base (1).en_US
dc.description.abstractBu çalışmada m-OCH₃ anilinden hazırlanan Schiff bazı (1) ile, iyot sübstitüye Schiff bazını sentezlemek amacıyla ; DMSO, I₂, H₂S0₄ ile reaksiyona sokulmuştur. Reaksiyon DMSO, I₂, H₂S0₄'li ortamda 100°C'de, geri soğutucu altında gerçekleştirilmiştir. Reaksiyon ortamının pH'ı yaklaşık 5 olarak belirlenmiştir. pH'ı 2 civarında yapılan deneyde azometin (-CH=N-) bağının kırıldığı tespit edilmiştir. Reaksiyon 100°C'de yaklaşık 10 saatlik sürede gerçekleştirilmiştir. İzole ürünlerin (2,3) yapısı kütle, IR, UV, ¹³C-NMR, ¹H-NMR ve elementel analiz ile tayin edilmiştir. Reaksiyon koşullarında iyot, naftolik Schiff bazının (1) fenil halkasına sübstitüye olmuştur.en_US
dc.language.isoengen_US
dc.publisherAnadolu Üniversitesien_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectAromaticen_US
dc.subjectElectrophilicen_US
dc.subjectHalogenationen_US
dc.subjectLode Substitutionen_US
dc.subjectAromatiken_US
dc.subjectElektrofıliken_US
dc.subjectHalojenlemeen_US
dc.subjectİyot Sübstitüsyonuen_US
dc.titleThe Synthesis of 1-(N-2’-Iodo-5,-Methoxyphenyuminomethyl)-2-Naphtol and (1-N-2’,4’- Diiodo-5'-Methoxyphenyliminomethyl)-2-Naphtolen_US
dc.title.alternative1-(N-2'-İyodo-5’-Metoksifeniliminometil)-2-Naftol ve 1-(N2’,4'-Dii Yodo-5’-Metoksifeniliminometil)-2-Naftol'ün Sentezien_US
dc.typearticleen_US
dc.relation.journalAnadolu Üniversitesi Bilim ve Teknoloji Dergisi A - Uygulamalı Bilimler ve Mühendisliken_US
dc.relation.publicationcategoryMakale - Ulusal Hakemli Dergi - Kategorisizen_US


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