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dc.contributor.authorÜnver, Hakan
dc.contributor.authorYılmaz, Filiz
dc.date.accessioned2019-10-20T09:14:25Z
dc.date.available2019-10-20T09:14:25Z
dc.date.issued2016
dc.identifier.issn2073-4344
dc.identifier.urihttps://dx.doi.org/10.3390/catal6090147
dc.identifier.urihttps://hdl.handle.net/11421/17236
dc.descriptionWOS: 000384675300021en_US
dc.description.abstractThe hydrogenation activity of new N-acyl-benzotriazole Rh(I) and Ru(III) complexes in ionic liquid media is reported in this study. Both complexes were completely soluble in 1-butyl-3-methylimidazolium tetrafluoroborate, [bmim][BF4], and they were able to catalyze the hydrogenation of styrene and 1-octene. While ethylbenzene conversion in styrene hydrogenation reached 84% when the Ru complex was used, 100% conversion was obtained with the Rh complex at 393 K in 6 h. Additionally, total conversion in 1-octene hydrogenation reached 100% with the Rh complex in [bmim][BF4] media. The hydrogenation of styrene and 1-octene in dimethyl sulfoxide (DMSO) and toluene was also studied to compare the solvent effect on catalytic system. The effect of some catalytic parameters such as temperature, H-2 (g) pressure, and catalyst amount on the conversion was examined, and it was found that the conversion increased parallel to the increasing temperature and H-2 pressure. The recyclability of catalysts was also investigated, and it was revealed that the Rh complex in particular maintained the activity for at least 10 cycles.en_US
dc.description.sponsorshipScientific and Technological Research Council of Turkey (TUBITAK) [2211]en_US
dc.description.sponsorshipWe thank the Anadolu University Plant Drug and Scientific Research Center (AUBIBAM) for NMR measurements and The Scientific and Technological Research Council of Turkey (TUBITAK), 2211-Doctorate Grant Programme, for its financial support.en_US
dc.language.isoengen_US
dc.publisherMDPI AGen_US
dc.relation.isversionof10.3390/catal6090147en_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectN-Acyl-Benzotriazoleen_US
dc.subjectIonic Liquiden_US
dc.subjectHydrogenationen_US
dc.subjectCatalysisen_US
dc.subjectRhodiumen_US
dc.subjectRutheniumen_US
dc.titleSynthesis, Characterization, and Catalytic Hydrogenation Activity of New N-Acyl-Benzotriazole Rh(I) and Ru(III) Complexes in [bmim][BF4]en_US
dc.typearticleen_US
dc.relation.journalCatalystsen_US
dc.contributor.departmentAnadolu Üniversitesi, Fen Fakültesi, Fizik Bölümüen_US
dc.identifier.volume6en_US
dc.identifier.issue9en_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.contributor.institutionauthorYılmaz, Filiz


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