dc.contributor.author | Ünver, Hakan | |
dc.date.accessioned | 2019-10-20T09:14:25Z | |
dc.date.available | 2019-10-20T09:14:25Z | |
dc.date.issued | 2018 | |
dc.identifier.issn | 0340-4285 | |
dc.identifier.issn | 1572-901X | |
dc.identifier.uri | https://dx.doi.org/10.1007/s11243-018-0252-2 | |
dc.identifier.uri | https://hdl.handle.net/11421/17237 | |
dc.description | WOS: 000446415000009 | en_US |
dc.description.abstract | A water-soluble dinuclear Cu(II) complex, [Cu-2(OOCC6H4Br)(OCH3)(C10H8N2)(2)(ClO4)(2)] (4-bromobenzoic acid = HOOC-C6H4Br; 2-2'-bipyridyl = C10H8N2) was synthesized and characterized by X-ray crystallography. The complex was investigated as a selective catalyst for the mild oxidation of primary and secondary alcohols in the presence of hydrogen peroxide as oxidant at 70 degrees C in water. The complex proved to be an active catalyst for production of the corresponding aldehydes or ketones. Thus, cinnamyl alcohol, benzyl alcohol, 1-phenyl ethanol and 2-butanol were quantitatively oxidized in 6 h, using a low catalyst loading (1 mol%). | en_US |
dc.language.iso | eng | en_US |
dc.publisher | Springer | en_US |
dc.relation.isversionof | 10.1007/s11243-018-0252-2 | en_US |
dc.rights | info:eu-repo/semantics/closedAccess | en_US |
dc.title | Crystal structure of an alkoxide bridged dinuclear copper(II) complex: mild and selective oxidation of primary and secondary alcohols in water | en_US |
dc.type | article | en_US |
dc.relation.journal | Transition Metal Chemistry | en_US |
dc.contributor.department | Anadolu Üniversitesi, Fen Fakültesi, Fizik Bölümü | en_US |
dc.identifier.volume | 43 | en_US |
dc.identifier.issue | 7 | en_US |
dc.identifier.startpage | 641 | en_US |
dc.identifier.endpage | 646 | en_US |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |