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dc.contributor.authorYılmaz, Filiz
dc.contributor.authorMutlu, Aylin
dc.contributor.authorÜnver, Hakan
dc.contributor.authorKurtca, Mehmet
dc.contributor.authorKani, İbrahim
dc.date.accessioned2019-10-20T09:14:28Z
dc.date.available2019-10-20T09:14:28Z
dc.date.issued2010
dc.identifier.issn0896-8446
dc.identifier.urihttps://dx.doi.org/10.1016/j.supflu.2010.04.014
dc.identifier.urihttps://hdl.handle.net/11421/17251
dc.descriptionWOS: 000280376600010en_US
dc.description.abstractPd(II) complexes with the tridentate ligands heptadecafluorodecyl-thiophene-2-carboxylate (L-1 = SOSRf1, R-f1 = (CH2)(2)(CF2)(7)CF3) and heptadecafluorononil thiophene-2-carboxylate (L-2 = SOORf2, R-f2 =(CH2)(CF2)(7)CF3) have been synthesized, and their catalytic activities for the homogeneous hydrogenation of olefins have been studied with molecular hydrogen in scCO(2) and organic solvents. Both perfluoroalkylated-heterocycle ligands potentially have three donor atom sets (SOO/SOS). Depending on the soft-hard interaction between palladium and the donor atoms of the ligands, different activities for the Pd(II) complexes were observed. The nature of the solvent had an effect upon the hydrogenation of olefins. The effects of temperature and H-2 pressure on the hydrogenation of styrene were also investigateden_US
dc.description.sponsorshipScientific and Technological Research Council of Turkey (TUBITAK) [107T693]; Anadolu University, Medicinal Plants, Drugs and Scientific Research Center (AUBIBAM)en_US
dc.description.sponsorshipThis work was financially supported by The Scientific and Technological Research Council of Turkey (TUBITAK) (project no. 107T693). The authors wish to acknowledge Anadolu University, Medicinal Plants, Drugs and Scientific Research Center (AUBIBAM).en_US
dc.language.isoengen_US
dc.publisherElsevier Science BVen_US
dc.relation.isversionof10.1016/j.supflu.2010.04.014en_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectTridentateen_US
dc.subjectHydrogenationen_US
dc.subjectOlefinsen_US
dc.subjectSupercriticalen_US
dc.subjectPalladiumen_US
dc.subjectHomogeneousen_US
dc.titleHydrogenation of olefins catalyzed by Pd(II) complexes containing a perfluoroalkylated S,O-chelating ligand in supercritical CO2 and organic solventsen_US
dc.typearticleen_US
dc.relation.journalJournal of Supercritical Fluidsen_US
dc.contributor.departmentAnadolu Üniversitesi, Fen Fakültesi, Fizik Bölümüen_US
dc.identifier.volume54en_US
dc.identifier.issue2en_US
dc.identifier.startpage202en_US
dc.identifier.endpage209en_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.contributor.institutionauthorYılmaz, Filiz
dc.contributor.institutionauthorKani, İbrahim


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