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dc.contributor.authorÜnver, Hakan
dc.contributor.authorYılmaz, Filiz
dc.date.accessioned2019-10-20T14:27:48Z
dc.date.available2019-10-20T14:27:48Z
dc.date.issued2017
dc.identifier.issn0167-7322
dc.identifier.issn1873-3166
dc.identifier.urihttps://dx.doi.org/10.1016/j.molliq.2017.06.038
dc.identifier.urihttps://hdl.handle.net/11421/17839
dc.descriptionWOS: 000407535000106en_US
dc.description.abstractPalladium complexes of N-acylbenzotriazole derivative ligands were synthesized and characterized. The catalytic activities of complexes of ([PdLl (OAc)(2)] and [PdL2(OAc)(2)]) were investigated in relation to hydrogenation reactions of styrene, 1-octene and cyclohexene in [bmim][BF4] as greener reaction media 100% ethyl benzene conversion was obtained with both complexes in 1 h reaction time. Additionally, 100% 1-octene conversion was reached within the same period of time with [PdL2(OAc)(2)] complex. In cyclohexene hydrogenation, product formation reached up to 67% at 363 K with [PdLl (OAc)(2)] complex. Reusability tests were conducted under the highest product conversion conditions, and both catalysts were found to be efficient up to 5 cycles for all substrates. The other reaction parameters such as solvent effect, H-2 (g) pressure, n(s)/n(c) ratio were also investigateden_US
dc.description.sponsorshipScientific And Technological Research Council Of Turkey (TUBITAK)en_US
dc.description.sponsorshipThe authors are grateful to Anadolu University, Plant, Drug and Scientific Research Center (AUBIBAM) for NMR analyses and The Scientific And Technological Research Council Of Turkey (TUBITAK) for 2211 grant program.en_US
dc.language.isoengen_US
dc.publisherElsevieren_US
dc.relation.isversionof10.1016/j.molliq.2017.06.038en_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectN-Acylbenzotriazoleen_US
dc.subjectPalladiumen_US
dc.subjectIonic Liquiden_US
dc.subjectHydrogenationen_US
dc.titleNew palladium (II) complexes with Thiophene arid furan bridged N-Acylbenzotriazole ligands: Synthesis, characterization and hydrogenation activity in ionic liquiden_US
dc.typearticleen_US
dc.relation.journalJournal of Molecular Liquidsen_US
dc.contributor.departmentAnadolu Üniversitesi, Fen Fakültesi, Kimya Bölümüen_US
dc.identifier.volume241en_US
dc.identifier.startpage875en_US
dc.identifier.endpage880en_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US]
dc.contributor.institutionauthorYılmaz, Filiz


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