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dc.contributor.authorPalmisano, Giovanni
dc.contributor.authorYurdakal, Sedat
dc.contributor.authorAugugliaro, Vincenzo
dc.contributor.authorLoddo, Vittorio
dc.contributor.authorPalmisano, Leonardo
dc.date.accessioned2019-10-20T14:27:50Z
dc.date.available2019-10-20T14:27:50Z
dc.date.issued2007
dc.identifier.issn1615-4150
dc.identifier.urihttps://dx.doi.org/10.1002/adsc.200600435
dc.identifier.urihttps://hdl.handle.net/11421/17858
dc.descriptionWOS: 000246040000026en_US
dc.description.abstractThe photocatalytic oxidation of 4-methoxybenzyl alcohol to p-anisaldehyde (PAA) was performed in water with organic-free suspensions of home-prepared and commercial titanium dioxide (TiO2) catalysts. The nanostructured TiO2 samples were synthesised by boiling aqueous solutions of titanium tetrachloride (TiCl4) under mild conditions, for different times. The crystallinity increased with the boiling time. The 4-methoxybenzyl alcohol oxidation rate followed the same pattern but the highest yield (41.5% mol) to PAA was found for the least crystalline sample, that showed a quantum efficiency of 0.116%. A comparison with two commercial TiO2 samples showed that all the home-prepared catalysts exhibited a PAA yield higher than that of commercial ones. The only by-products present were traces of 4-methoxybenzoic acid and aliphatic products, carbon dioxide being the other main oxidation product.en_US
dc.language.isoengen_US
dc.publisherWiley-V C H Verlag GMBHen_US
dc.relation.isversionof10.1002/adsc.200600435en_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectP-Anisaldehyde Productionen_US
dc.subjectPhotocatalysisen_US
dc.subjectSelective Oxidationen_US
dc.subjectTitanium Dioxideen_US
dc.titlePhotocatalytic selective oxidation of 4-methoxybenzyl alcohol to aldehyde in aqueous suspension of home-prepared titanium dioxide catalysten_US
dc.typearticleen_US
dc.relation.journalAdvanced Synthesis & Catalysisen_US
dc.contributor.departmentAnadolu Üniversitesi, Fen Fakültesi, Kimya Bölümüen_US
dc.identifier.volume349en_US
dc.identifier.issue6en_US
dc.identifier.startpage964en_US
dc.identifier.endpage970en_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US]


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