(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadekaflorodesill) (Metil) Sulfan Sübstitüe Titanyum Ftalosiyanin Türevle Rinin Sentezi ve Karakterizasyonu

Abstract

Symmetrically substituted phthalocyanine derivatives have been synthesized from the reaction of anhydrous metal salts of titanium with 4-(3.3.4,4,5,5.6,6,7,7,8.8,9,9.10,10,10-heptadecafluorodecylthio) phthalonitrile (3). 4-phthalonitrile (1) and 4-3,3,4.4,5,5,6,6,7,7,8,8,9.9,10,10,10-heptadecafluorodecylthiol) (2) in dry dimethylformamide as solvent and using K2CO3 as base via the common method of nucleophilic substitution of an activated nitro group in an aromatic ring. The compound 3.9,17,23-bis[ethane-1,1-p-phenol-2,2-p-phenokxy] phthalocyaninatocobalt (II) (F1T2CoPc) (4) was reacted with the compound 4-(3,3,4.4,5,5,6,6,7,7,8,8,9.9,10,10,10-heptadecafluorodecylthio) phthalocyaninatotinanium (IV) (5). which is similar to those synthesized in the past, to syhthesize a new derivative containing three phthalocyanines 3,9,17,23-bis[ethane-l,l-p>-(4-(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecylthio) phthalocyaninatotinanium (IV))-2,2-p-phenokxy]phthalocyaninatocobalt (II) (F1T2CoPc) (6). The synthesized molecules have been characterized by 19F NMR, HETCOR, MALDI-TOFF, UV-Vis and IR spectroscopies.

Simetrik sübstitüent içeren ftalosiyanin türevleri susuz titanyum metal tuzunun 4- (3,3,4;4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadekaflorodesiltiyo)ftalonitril (3) ile reaksiyonundan sentezlendi. Sentezlenen ftalonitril türevi çözücü olarak kuru dimetilformamid içerisinde 4-nitroftalonitril (1) ile 4-(3,3,4,4,5,5,6,6,7,7,8,8,9,9.10,10.10-heptadekaflorodesiltiyol) (2) ve baz olarak K2CO3 kullanılarak aromatik halkadaki nitro grubu üzerinden nükleofilik sübstitüsyon metoduna göre elde edildi. Yapısında üç tane ftalosiyanin bulunan yeni yapmın 3,9,17.23-bis[etan-l,l-p-(4-(3,3,4.4,5,5,6,6.7,7,8,8.9.9,10,10.10-heptadekafluorodesiltiyo) ftalosiyaninatotinanyum (IV))-2,2-p-fenoksijftalosiyaninatocobalt (II) (F1T2CoPc) (6) sentezi 4-(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10- heptadekafluorodesiltiyo) ftalosiyaninatotinanyum(IV) (F1T2CoPc) (4) ve 3,9,17,23-bis[etan-1,1-p-fenol-2,2-p-fenoksi]ftalosiyaninatocobalt (II) (CoPc) (5) bileşikleri ile gerçekleştirildi. Sentezlenen maddelerin karakterizasyonu 19F NMR, HETCOR, MALDI-TOFF, UV-Vis ve IR spektroskopik yöntemleri kullanılarak yapıldı.