Atmospheric ambient trace element concentrations of PM10 at urban and sub-urban sites: source apportionment and health risk estimation

Abstract

In this study, PM10 concentrations and elemental (Al, Fe, Sc, V, Cr, Mn, Co, Ni, Cu, Zn, As, Se, Mo, Ag, Cd, Sn, Sb, Ba, Pb, and Bi) contents of particles were determined in Duzce, Turkey. The particulate matter samplings were carried out in the winter and summer seasons simultaneously in both urban and sub-urban sampling sites. The average PM10 concentration measured in the winter season was 86.4 and 27.3 mu g/m(3), respectively, in the urban and sub-urban sampling sites, while it was measured as 53.2 and 34.7 mu g/m(3) in the summer season. According to the results, it was observed that the PM10 levels and the element concentrations reached higher levels, especially at the urban sampling site, in the winter season. The positive matrix factorization model (PMF) was applied to the data set for source apportionment. Analysis with the PMF model revealed six factors for both the urban (coal combustion, traffic, oil combustion, industry, biomass combustion, and soil) and sub-urban (industry, oil combustion, traffic, road dust, soil resuspension, domestic heating) sampling sites. Loadings of grouped elements on these factors showed that the major sources of the elements in the atmosphere of Duzce were traffic, fossil fuel combustion, and metal industry-related emissions.