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dc.contributor.authorKaraağaç, Dursun
dc.contributor.authorKürkçüoğlu, Güneş Süheyla
dc.contributor.authorŞenyel, Mustafa
dc.contributor.authorŞahin, Onur
dc.date.accessioned2019-10-20T09:13:59Z
dc.date.available2019-10-20T09:13:59Z
dc.date.issued2017
dc.identifier.issn0022-2860
dc.identifier.issn1872-8014
dc.identifier.urihttps://dx.doi.org/10.1016/j.molstruc.2017.02.013
dc.identifier.urihttps://hdl.handle.net/11421/17119
dc.descriptionWOS: 000397375800029en_US
dc.description.abstractIn this study, three new complexes (4aepyH)(2)[Ni(CN)(4)] (1), (4aepyH)(2)[Pd(CN)(4)] (2) and (4aepyH)(2)[Pt(CN)(4)] (3) [4aepy = 4-(2-aminoethyl)pyridine] have been synthesized and characterized by elemental, thermal, vibrational (FT-IR and Raman) and single-crystal X-ray diffraction techniques. The crystallographic analyses reveal that the complexes crystallize in the monoclinic system, space group C2/c. The asymmetric units of the complexes contain one M(II) ion, two cyanide ligands and one non coordinated the 4aepy ligand. Each M(II) ion is four coordinated with four cyanide-carbon atoms in a square planar geometry and the [M(CN)(4)](2-) anions act as a counter ion. The 4aepyH cations in the complexes compose of the protonation of the 4aepy. The vibrational spectral data also supported to the crystal structures of the complexes. Thermal stabilities and decomposition products of the complexes were investigated in the temperature range 40-700 degrees C in the static air atmosphereen_US
dc.language.isoengen_US
dc.publisherElsevier Science BVen_US
dc.relation.isversionof10.1016/j.molstruc.2017.02.013en_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectTetracyanometallate Complexen_US
dc.subject4-(2-Aminoethyl)Pyridinium Complexen_US
dc.subjectC-H Center Dot Center Dot Center Dot M Interactionen_US
dc.subjectHydrogen Bond Interactionen_US
dc.subjectCrystal Structureen_US
dc.subjectVibrational Spectraen_US
dc.titleSynthesis, spectroscopic, thermal and structural properties of 4-(2-aminoethyl)pyridinium tetracyanometallate(II) complexesen_US
dc.typearticleen_US
dc.relation.journalJournal of Molecular Structureen_US
dc.contributor.departmentAnadolu Üniversitesi, Fen Fakültesi, Fizik Bölümüen_US
dc.identifier.volume1136en_US
dc.identifier.startpage281en_US
dc.identifier.endpage287en_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.contributor.institutionauthorŞenyel, Mustafa


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