Yazar "Çetinkaya, Bekir" için listeleme
-
1-Pentamethylbenzyl-3-(n)buthylbenzimidazolesilver(I)bromide complex: Synthesis, characterization and DFT calculations
Kunduracıoğlu, Ahmet; Tamer, Ömer; Avcı, Davut; Kani, İbrahim; Atalay, Yusuf; Çetinkaya, Bekir (Pergamon-Elsevier Science LTD, 2014)A novel NHC complex of silver(I) ion, 1-pentamethylbenzyl-3-(n)buthylbenzimidazolesilver(I)bromide, was prepared and fully characterized by single crystal X-ray structure determination. FT-IR, NMR and UV-vis spectroscopies ... -
N,N,N ',N '-Tetrakis(2-hydroxyethyl)ethylenediamine palladium(II) complex as efficient catalyst for the Suzuki/Miyaura reaction in water
Gülcemal, Süleyman; Kani, İbrahim; Yılmaz, Filiz; Çetinkaya, Bekir (Pergamon-Elsevier Science LTD, 2010)A new water soluble palladium(II) complex (2) derived from N,N,N',N'-tetrakis(2-hydroxyethyl)ethylenediamine (edteH(4)) (1) was synthesized in high yield and characterized by (1)H, (13)C, HMQC and COSY NMR spectroscopy. ... -
A New Application Area for Ag-NHCs: CO2 Fixation Catalyst
Taşçı, Zeynep; Kunduracıoğlu, Ahmet; Kani, İbrahim; Çetinkaya, Bekir (Wiley-V C H Verlag GMBH, 2012)The first example of the silver-NHC catalyzed cycloaddition of CO2 to terminal epoxides is reported. The choice of NHC substituents, halides and the nature of additives were determined to be important. Ionic [(Cnmim)2Ag]2[Ag2Br4] ... -
(NHC)-Pd(II) complexes with hydrophilic Nitrogen ligands; catalytic properties in neat water
Türkmen, Hayati; Gök, Lütfiye; Kani, İbrahim; Çetinkaya, Bekir (Scientific Technical Research Council Turkey-Tubitak, 2013)The cleavage reactions of the dimers [(NHC)PdX2](2) with hydrophilic N-donors, L, a ff orded the mixedligand complexes of the type trans-[(NHC)LPdX2] (X = Cl or Br; NHC = 1,3-dialkylbenzimidazol-2-ylidene (BIm) or bis(imino) ... -
Ruthenium(II) complexes bearing pyridine-based tridentate and bidentate ligands: catalytic activity for transfer hydrogenation of aryl ketones
Dayan, Osman; Dayan, Serkan; Kani, İbrahim; Çetinkaya, Bekir (Wiley, 2012)Ru(II) complexes of the general formula [RuCl2('NNN??')(L)] (1: 'N?=?Nb, L?=?MeOH; 2: 'N?=?Nb, L?=?CH3CN; 3: 'N?=?Nd, L?=?CH3CN; 4: 'N?=?Np, L?=?CH3CN), [Ru(p-cymene)(NN?ab)Cl]Cl (5a: N?Na?=?2,2'-bipyridine; 5b: ... -
Synthesis, characterization, and reactivity of ruthenium(II) complexes containing eta(6)-arene-eta(1)-pyrazole ligands
Kırkar, Belgin Tuncel; Türkmen, Hayati; Kani, İbrahim; Çetinkaya, Bekir (Pergamon-Elsevier Science LTD, 2012)New ruthenium(II) complexes containing eta(6)-arene-eta(1)-pyrazole ligands were synthesized and characterized by elemental analysis and spectroscopic methods. In addition, the molecular structure of di-chloro-3,5-dimeth ... -
Transfer Hydrogenation of Aryl Ketones with Half-Sandwich RuII Complexes That Contain Chelating Diamines
Türkmen, Hayati; Kani, İbrahim; Çetinkaya, Bekir (Wiley-V C H Verlag GMBH, 2012)In a comparative study, half-sandwich complexes of RuII (1) with pyridine-based chelating diamine [NN = 2-aminomethylpiperidine (ampi), a; 2-aminomethylpyridine (ampy), b; 8-aminoquaniline (aquan), c; 4,4'-dimethyl-2,2'-bipyridine ...