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dc.contributor.authorBirlik, Ebru
dc.contributor.authorBüyüktiryaki, Sibel
dc.contributor.authorErsöz, Arzu
dc.contributor.authorDenizli, Adil
dc.contributor.authorSay, Rıdvan
dc.date.accessioned2019-10-19T11:17:48Z
dc.date.available2019-10-19T11:17:48Z
dc.date.issued2006
dc.identifier.issn0149-6395
dc.identifier.urihttps://dx.doi.org/10.1080/01496390600851400
dc.identifier.urihttps://hdl.handle.net/11421/11859
dc.descriptionWOS: 000241035600002en_US
dc.description.abstractWe have studied a new method for the preparation of Th(IV)-imprinted chitosan-phthalate particles, which can considerably enhance the adsorption capacity and selectivity of thorium ions. In this study, chitosan-phthalate was used as the complexing monomer, Th(IV) as template, epichlorohydrin as crosslinking agent. Initially, chitosan was modified with phthalic anhydrides and complex formation occured between carboxylic acid functional groups and Th(IV) ions. Secondly, particles were crosslinked with epichlorohydrin. After the removal of Th(IV) ions, thorium solid phase extraction (SPE) on the Th(IV) ion-imprinted particles from aqueous solutions containing their different amounts, selectivity study of thorium versus other interfering metal ions mixture which are Fe3+, La3+, and Mn2+ and distribution and selectivity coefficients were reported here. A comparison of the selectivity coefficient of Th(IV)-imprinted chitosan-phthalate particles with the selectivity coefficient of non-imprinted polymers showed that the imprinted matrix for Th(IV)/Fe(III), Th(IV)/La(III) and Th(IV)/Mn(II) was 8.35, 8.75 and 10.81 times greater than non-imprinted matrix, respectively.en_US
dc.language.isoengen_US
dc.publisherTaylor & Francis Incen_US
dc.relation.isversionof10.1080/01496390600851400en_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectMipen_US
dc.subjectSpeen_US
dc.subjectIcp-Aesen_US
dc.subjectThorium Determinationen_US
dc.subjectChitosanen_US
dc.titleSelective separation of thorium using ion imprinted chitosan-phthalate particles via solid phase extractionen_US
dc.typearticleen_US
dc.relation.journalSeparation Science and Technologyen_US
dc.contributor.departmentAnadolu Üniversitesi, Bitki, İlaç ve Bilimsel Araştırmalar Merkezien_US
dc.identifier.volume41en_US
dc.identifier.issue14en_US
dc.identifier.startpage3109en_US
dc.identifier.endpage3121en_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.contributor.institutionauthorBüyüktiryaki, Sibel
dc.contributor.institutionauthorErsöz, Arzu
dc.contributor.institutionauthorSay, Rıdvan


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