dc.contributor.author | Ceyhan, Gökhan | |
dc.contributor.author | Köse, Muhammet | |
dc.contributor.author | Tumer, Mehmet | |
dc.contributor.author | Dal, Hakan | |
dc.date.accessioned | 2019-10-20T09:03:17Z | |
dc.date.available | 2019-10-20T09:03:17Z | |
dc.date.issued | 2015 | |
dc.identifier.issn | 1386-1425 | |
dc.identifier.uri | https://dx.doi.org/10.1016/j.saa.2015.01.114 | |
dc.identifier.uri | https://hdl.handle.net/11421/16678 | |
dc.description | WOS: 000351980400002 | en_US |
dc.description | PubMed ID: 25698438 | en_US |
dc.description.abstract | A polymeric potassium complex of p-nitrophenol was synthesized and characterized by analytical and spectroscopic techniques. Molecular structure of the complex was determined by single crystal X-ray diffraction study. X-ray structural data show that crystals contain polymeric K+ complex of p-nitrophenol. Asymmetric unit consists of one p-nitrophenolate, one K+ ion and one water molecule. All bond lengths and angles in the phenyl rings have normal Csp2-Csp2 values and are in the expected ranges. The p-nitrophenolate is close to planar with small distortions by some atoms. Each potassium ion in the polymeric structure is identical and eight-coordinate, bonded to four nitro, two phenolate oxygen atoms from five p-nitrophenolate ligands and two oxygen atoms from two water molecules. Electronic, electrochemical, photoluminescence and thermal properties of the complex were also investigated. | en_US |
dc.description.sponsorship | Scientific & Technological Research Council of Turkey (TUBITAK) [109T071] | en_US |
dc.description.sponsorship | We are grateful to The Scientific & Technological Research Council of Turkey (TUBITAK) (Project no. 109T071) for the financial support of this research. | en_US |
dc.language.iso | eng | en_US |
dc.publisher | Pergamon-Elsevier Science LTD | en_US |
dc.relation.isversionof | 10.1016/j.saa.2015.01.114 | en_US |
dc.rights | info:eu-repo/semantics/closedAccess | en_US |
dc.subject | P-Nitrophenol | en_US |
dc.subject | Potassium Complex | en_US |
dc.subject | X-Ray Structure | en_US |
dc.subject | Coordination Polymer | en_US |
dc.subject | Electrochemical | en_US |
dc.subject | Photoluminescence | en_US |
dc.title | Structural characterization, electrochemical, photoluminescence and thermal properties of potassium ion-mediated coordination polymer | en_US |
dc.type | article | en_US |
dc.relation.journal | Spectrochimica Acta Part A-Molecular and Biomolecular Spectroscopy | en_US |
dc.contributor.department | Anadolu Üniversitesi, Fen Fakültesi, Fizik Bölümü | en_US |
dc.identifier.volume | 142 | en_US |
dc.identifier.startpage | 8 | en_US |
dc.identifier.endpage | 14 | en_US |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
dc.contributor.institutionauthor | Dal, Hakan | |