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dc.contributor.authorTaş, Murat
dc.contributor.authorCamur, Seval
dc.contributor.authorKılıç, Yalçın
dc.contributor.authorDal, Hakan
dc.date.accessioned2019-10-20T09:03:23Z
dc.date.available2019-10-20T09:03:23Z
dc.date.issued2012
dc.identifier.issn2194-4946
dc.identifier.issn2196-7105
dc.identifier.urihttps://dx.doi.org/10.1524/zkri.2012.1551
dc.identifier.urihttps://hdl.handle.net/11421/16699
dc.descriptionWOS: 000313928000005en_US
dc.description.abstractThe two complexes of Bis(4-aminosalicylato-O) bis(N,N-dimethylethylenediamine)Ni(II) with different colors, were synthesized by the reaction between sodium salt of 4-aminosalicylic acid (PAS-Na), Ni(NO3)(2) center dot 6H(2)O and N,N-dimethylethylenediamine in the ethanol water mixture. In the complexes, each Ni(II) atom was in a distorted octahedral environment, was coordinated apically by two 4-aminosalicylato-O atoms and equatorially by two the N,N-dimethylethylenediamine N atoms. The crystal structures (monoclinic, P21/n space group) of the complexes, comprise mononuclear {Ni(NH2OHC6H3COO)(2) center dot [NH2CH2CH2N(CH3)(2)](2)} species and the Ni(II) atoms were located on a crystallographic inversion centre. The bond lengths and bond angles were nearly same with showing small difference as approximately 1% in coordination bonds lengths which caused the different colors for complexes. The N-H center dot center dot center dot O, C-H center dot center dot center dot O and C-H center dot center dot center dot pi inter-molecular interactions, extended the molecules through the three axes to form three dimensional network.en_US
dc.language.isoengen_US
dc.publisherWalter De Gruyter GMBHen_US
dc.relation.isversionof10.1524/zkri.2012.1551en_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subject4-Aminosalicylic Aciden_US
dc.subject4-Amino-2-Hydroxybenzoic Aciden_US
dc.subjectPara-Aminosalicylic Aciden_US
dc.subjectMixed Ligand Complexen_US
dc.subjectNickel(Ii) Complexesen_US
dc.titleThe two Bis(4-aminosalicylato-O) bis(N,N-dimethylethylenediamine)Ni(II) complexesen_US
dc.typearticleen_US
dc.relation.journalZeitschrift Fur Kristallographie-Crystalline Materialsen_US
dc.contributor.departmentAnadolu Üniversitesi, Fen Fakültesi, Fizik Bölümüen_US
dc.identifier.volume227en_US
dc.identifier.issue12en_US
dc.identifier.startpage837en_US
dc.identifier.endpage842en_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.contributor.institutionauthorDal, Hakan


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