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dc.contributor.authorAy, Burak
dc.contributor.authorDoğan, Nurhayat
dc.contributor.authorYıldız, Emel
dc.contributor.authorKani, İbrahim
dc.date.accessioned2019-10-20T09:13:26Z
dc.date.available2019-10-20T09:13:26Z
dc.date.issued2015
dc.identifier.issn0277-5387
dc.identifier.urihttps://dx.doi.org/10.1016/j.poly.2014.12.035
dc.identifier.urihttps://hdl.handle.net/11421/16910
dc.descriptionWOS: 000352748700022en_US
dc.description.abstractA novel three dimensional (3D) coordination polymer [Sm(pic)(2)(pydc)(4)(H2O)](n) (pydc = pyridine-2,5-dicarboxylate, Hpic = picolinic acid) (1) has been synthesized hydrothermally and characterized by elemental analysis, FT-IR, TG/DTA, single-crystal X-ray diffraction analysis and powder X-ray diffraction (PXRD). This compound crystallizes in the monoclinic space group P2(1/c) with cell parameters a = 9.3041(13)angstrom, b= 14.216(2)angstrom, c = 10.5401(15) angstrom, V= 1387.72(30) angstrom(3) and Z = 4. complex 1 has a distinct 3D open-framework architecture due to the presence of pitolinic ligands, which are converted from 2,5-pydc ligands by in-situ decarboxylation under the hydrothermal conditions. The compound exhibits strong luminescent emissions because of the f-f transitions of the Sm(III) ion at room temperature. According to TGA/DTA analysis, the coordination polymer is thermally stable up to similar to 300 degrees Cen_US
dc.description.sponsorshipResearch Unit of Cukurova University [FEF2013YL23]; Medicinal Plants and Medicine Research Centre of Anadolu University, Eskisehir, Turkeyen_US
dc.description.sponsorshipThe authors gratefully acknowledge financial support from the Research Unit of Cukurova University (Grant No. FEF2013YL23) and the Medicinal Plants and Medicine Research Centre of Anadolu University, Eskisehir, Turkey, for the use of X-ray diffractometer.en_US
dc.language.isoengen_US
dc.publisherPergamon-Elsevier Science LTDen_US
dc.relation.isversionof10.1016/j.poly.2014.12.035en_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectHydrothermal Synthesisen_US
dc.subjectX-Ray Structuresen_US
dc.subject2,5-Pyridinedicarboxylic Aciden_US
dc.subjectSamarium(Lll) Coordination Polymeren_US
dc.subjectDecarboxylationen_US
dc.titleA novel three dimensional samarium(III) coordination polymer with an unprecedented coordination mode of the 2,5-pyridinedicarboxylic acid ligand: Hydrothermal synthesis, crystal structure and luminescence propertyen_US
dc.typearticleen_US
dc.relation.journalPolyhedronen_US
dc.contributor.departmentAnadolu Üniversitesi, Fen Fakültesi, Fizik Bölümüen_US
dc.identifier.volume88en_US
dc.identifier.startpage176en_US
dc.identifier.endpage181en_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.contributor.institutionauthorKani, İbrahim


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