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dc.contributor.authorKaraağaç, Dursun
dc.contributor.authorKürkçüoğlu, Güneş Süheyla
dc.contributor.authorYeşilel, Okan Zafer
dc.contributor.authorHökelek, Tuncer
dc.contributor.authorSüzen, Yasemin
dc.date.accessioned2019-10-20T09:14:04Z
dc.date.available2019-10-20T09:14:04Z
dc.date.issued2013
dc.identifier.issn0020-1693
dc.identifier.issn1873-3255
dc.identifier.urihttps://dx.doi.org/10.1016/j.ica.2013.06.047
dc.identifier.urihttps://hdl.handle.net/11421/17142
dc.descriptionWOS: 000324325200010en_US
dc.description.abstractIn this study, six new complexes (3ampyH)(2)[Ni(CN)(4)] (1), (3ampyH)(2)[Pd(CN)(4)] (2), (3ampyH)(2)[Pt(CN)(4)] (3), (4ampyH)(2)[Ni(CN)(4)] (4), (4ampyH)(2)[Pd(CN)(4)] (5) and (4ampyH)(2)[Pt(CN)(4)] (6) (3ampy = 3-aminomethylpyridine and 4ampy = 4-aminomethylpyridine) have been synthesized and characterized by spectroscopic, elemental and thermal analyses, and single crystal X-ray diffraction techniques. Complexes 1, 2 and 3 crystallize in the monoclinic system, space groups P2(1)/c, C2 and C2, respectively, whereas complexes 4, 5 and 6 crystallize in the triclinic system, space groups P (1) over bar. The asymmetric units contain one halves of the [M(CN)(4)](2) anions and the 3ampyH or the 4ampyH cations, where M is Ni(II), Pd(II) or Pt(II), respectively. The metal atoms are located on inversion centres and each metal atom is coordinated in a distorted square planar geometry by the four symmetry related C atoms from four cyano ligandsen_US
dc.description.sponsorshipEskisehir Osmangazi University [201219A202]en_US
dc.description.sponsorshipThis work was supported by the Research Fund of Eskisehir Osmangazi University. Project number: 201219A202. Raman spectra were recorded at Anadolu University, Department of Physics. The authors wish to thank Prof. Dr. Mustafa Senyel and Mrs. Tulay Tiras for the Raman measurements.en_US
dc.language.isoengen_US
dc.publisherElsevier Science Saen_US
dc.relation.isversionof10.1016/j.ica.2013.06.047en_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectTetracyanometallate Complexesen_US
dc.subjectAminomethylpyridiniumen_US
dc.subjectCrystal Structureen_US
dc.subjectC-H Center Dot Center Dot Center Dot M Interactionen_US
dc.subjectHydrogen Bond Interactionsen_US
dc.subjectVibrational Analysesen_US
dc.titleSyntheses, crystal structures, spectroscopic and thermal analyses of 3-and 4-aminomethylpyridinium tetracyanometallate(II) complexesen_US
dc.typearticleen_US
dc.relation.journalInorganica Chimica Actaen_US
dc.contributor.departmentAnadolu Üniversitesi, Fen Fakültesi, Fizik Bölümüen_US
dc.identifier.volume406en_US
dc.identifier.startpage73en_US
dc.identifier.endpage80en_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.contributor.institutionauthorSüzen, Yasemin


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