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dc.contributor.authorKaraağaç, Dursun
dc.contributor.authorKürkçüoğlu, Güneş Süheyla
dc.contributor.authorHökelek, Tuncer
dc.contributor.authorYeşilel, Okan Zafer
dc.contributor.authorSüzen, Yasemin
dc.descriptionWOS: 000317249500006en_US
dc.description.abstractThe heteronuclear complex, [Cd(NH3)(2)(mu-ampy)Pd(mu-CN)(2)(CN)(2)], (1) (ampy = 4-aminomethylpyridine), was synthesized and characterized by vibrational (FT-IR and Raman) spectroscopy, elemental and thermal analyses and single crystal X-ray diffraction techniques. The complex crystallizes in the triclinic system, space group P (1) over bar. The Cd(II) ion exhibits a distorted octahedral coordination by two different N-atoms from two symmetrically equivalent ampy ligands, two ammine ligands and two bridging cyano groups, whereas the Pd(II) ion has square planar coordination and is coordinated by four cyano ligands. The tetracyanopalladate(l) anion is coordinated to the adjacent two Cd(II) ions to generate a one-dimensional chain. The adjacent 1D chains are connected by the mu-ampy bridging ligands to form a 2D network. The 2D layers are further linked by Pd center dot center dot center dot pi and hydrogen bonding interactions to generate a 3D supramolecular network. The decomposition reaction takes places in the temperature range of 40-900 degrees C in the static air atmosphere.en_US
dc.description.sponsorshipEskisehir Osmangazi University [201219A202]en_US
dc.description.sponsorshipThis work was supported by the Research Fund of Eskisehir Osmangazi University. Project number: 201219A202. Raman spectrum was recorded at Anadolu University, Department of Physics. The authors wish to thank Prof. Dr. Mustafa Senyel and Mrs. Tulay Tiras for the Raman measurements.en_US
dc.publisherWalter De Gruyter GMBHen_US
dc.subjectHeteronuclear Complexen_US
dc.subjectTetracyanopalladate Complexen_US
dc.subject4-Aminomethylpyridine Complexen_US
dc.subjectStructure Analysisen_US
dc.subjectVibrational Spectrumen_US
dc.titleTwo dimensional cyano-bridged heteropolynudear complex containing Pd center dot center dot center dot pi interactionsen_US
dc.relation.journalZeitschrift Fur Kristallographie-Crystalline Materialsen_US
dc.contributor.departmentAnadolu Üniversitesi, Fen Fakültesi, Fizik Bölümüen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.contributor.institutionauthorSüzen, Yasemin

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