| dc.contributor.author | Yılmaz, Filiz | |
| dc.contributor.author | Özer, Metin | |
| dc.contributor.author | Kani, İbrahim | |
| dc.contributor.author | Bekaroğlu, özer | |
| dc.date.accessioned | 2019-10-20T09:14:28Z | |
| dc.date.available | 2019-10-20T09:14:28Z | |
| dc.date.issued | 2009 | |
| dc.identifier.issn | 1011-372X | |
| dc.identifier.issn | 1572-879X | |
| dc.identifier.uri | https://dx.doi.org/10.1007/s10562-009-9959-1 | |
| dc.identifier.uri | https://hdl.handle.net/11421/17249 | |
| dc.description | WOS: 000267330300055 | en_US |
| dc.description.abstract | A fluoroalkene-soluble tetrakis[heptadecafluorononyl]-substituted Pd(II)-phthalocyanine complex has been studied for olefin (styrene, 1-octene, trans-2-octene and cyclohexene) hydrogenation with molecular hydrogen in an organic/fluorous biphasic system [n-hexane/perfluoromethyl cyclohexane (PFMCH)]. The palladium complex was found to be an active catalyst for styrene (100% conversion, TON = 634) and 1-octene (92%, TON = 596) at 80 degrees C and 15 bar of H-2 after 6 h of reaction time. The catalyst was recycled in nine consecutive reactions for the hydrogenation of styrene without the loss of activity or metal contamination. | en_US |
| dc.description.sponsorship | Turkish Academy of Sciences (TUBA; Marmara University; Anadolu University Medicinal Plants, Drugs and Scientific Research Center (AUBIBAM); Research Fund of DPT [2003K120810]; The Scientific and Technological Research Council of Turkey (TUBITAK) [108T272] | en_US |
| dc.description.sponsorship | This work was supported partly by the Turkish Academy of Sciences (TUBA), Marmara University, Anadolu University Medicinal Plants, Drugs and Scientific Research Center (AUBIBAM), the Research Fund of DPT (Project No: 2003K120810) and The Scientific and Technological Research Council of Turkey (TUBITAK) (Project No: 108T272). | en_US |
| dc.language.iso | eng | en_US |
| dc.publisher | Springer | en_US |
| dc.relation.isversionof | 10.1007/s10562-009-9959-1 | en_US |
| dc.rights | info:eu-repo/semantics/closedAccess | en_US |
| dc.subject | Biphasic Catalysis | en_US |
| dc.subject | Hydrogenation | en_US |
| dc.subject | Phthalocyanine | en_US |
| dc.subject | Palladium Complex | en_US |
| dc.subject | Fluorous Solvent | en_US |
| dc.title | Catalytic Activity of a Thermoregulated, Phase-Separable Pd(II)-perfluoroalkylphthalocyanine Complex in an Organic/Fluorous Biphasic System: Hydrogenation of Olefins | en_US |
| dc.type | article | en_US |
| dc.relation.journal | Catalysis Letters | en_US |
| dc.contributor.department | Anadolu Üniversitesi, Fen Fakültesi, Fizik Bölümü | en_US |
| dc.identifier.volume | 130 | en_US |
| dc.identifier.issue | 3.Nis | en_US |
| dc.identifier.startpage | 642 | en_US |
| dc.identifier.endpage | 647 | en_US |
| dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
| dc.contributor.institutionauthor | Yılmaz, Filiz | |
| dc.contributor.institutionauthor | Kani, İbrahim | |
