Effect of salt modification and acid activation on ethylene adsorption properties of sepiolite

Abstract

The adsorption of ethylene (C2H4) on sepiolite from EskiAYehir, Turkey and on its salt modified forms (NaS, KS, CaS and MgS) and treated with 1, 3 and 5 M HCl solutions (SH, S3H and S5H) was investigated. The sepiolite samples were characterized using X-ray diffraction, X-ray fluorescence, thermogravimety, differential thermal analysis and N-2 adsorption methods. The C2H4 adsorption isotherms of all clay samples were obtained at 20 A degrees C up to 37 kPa. The uptake of C2H4 decreased as HS > CaS > NaS > S > MgS > KS > H3S > H5S for sepiolite samples. Capacity of sepiolites for C2H4 ranged from 0.478 to 0.622 mmol/g. It was found that the adsorbed amount of C2H4 on sepiolite samples decreased with increasing acid concentrations.