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dc.contributor.authorPalmisano, Giovanni
dc.contributor.authorLoddo, Vittorio
dc.contributor.authorAugugliaro, Vincenzo
dc.contributor.authorPalmisano, Leonardo
dc.contributor.authorYurdakal, Sedat
dc.date.accessioned2019-10-20T14:27:50Z
dc.date.available2019-10-20T14:27:50Z
dc.date.issued2007
dc.identifier.issn0001-1541
dc.identifier.urihttps://dx.doi.org/10.1002/aic.11137
dc.identifier.urihttps://hdl.handle.net/11421/17859
dc.descriptionWOS: 000245150800018en_US
dc.description.abstractThe oxidation of nitrobenzene and phenylamine has been carried out by heterogeneous photocatalysis in aqueous suspensions of commercial TiO2. The photoreactivity results indicate that two reaction pathways occur in parallel with both substrates from the start of irradiation: partial oxidation to monohydroxy derivatives and mineralization. The first pathway involves the entering of radical HO center dot into the aromatic ring giving rise to monohydroxy derivatives, and the second one involves the total oxidation of the substrates to CO2. The partial oxidation of nitrobenzene produces all the three possible monohydroxy derivatives, while that of phenylamine only produces the ortho- and para-isomers. The extent of adsorption in the dark was found to be about 8% mol for nitrobenzene, while the amounts were not detectable for phenylamine. The Langmuir-Hinshelwood approach has been satisfactorily applied for modeling the photoreactivity results, and the values of the kinetic model parameters have been determineden_US
dc.language.isoengen_US
dc.publisherJohn Wiley & Sons Incen_US
dc.relation.isversionof10.1002/aic.11137en_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectPartial Oxidationen_US
dc.subjectNitrobenzeneen_US
dc.subjectPhenylamineen_US
dc.subjectHeterogeneous Photocatalysisen_US
dc.subjectReaction Pathwayen_US
dc.subjectKineticsen_US
dc.subjectTio2en_US
dc.titlePhotocatalytic oxidation of nitrobenzene and phenylamine: Pathways and kineticsen_US
dc.typearticleen_US
dc.relation.journalAiche Journalen_US
dc.contributor.departmentAnadolu Üniversitesi, Fen Fakültesi, Kimya Bölümüen_US
dc.identifier.volume53en_US
dc.identifier.issue4en_US
dc.identifier.startpage961en_US
dc.identifier.endpage968en_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US]


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