Yazar "Kani, İbrahim" için Fen Fakültesi listeleme
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Molecular docking, Hirshfeld surface, structural, spectroscopic, electronic, NLO and thermodynamic analyses on novel hybrid compounds containing pyrazole and coumarin cores
Sert, Yusuf; Gümüş, Mehmet; Gökçe, Halil; Kani, İbrahim; Koca, İrfan (Elsevier Science BV, 2018)The target compound 3-(3-(4-chlorobenzoyl)-1-phenyl-1H-pyrazole-5-carbonyl)-7-methoxy-2H-chromen-2-one was characterized by FT-IR, Laser-Raman, NMR chemical shift, UV-Vis. and single-crystal X-Ray diffraction spectroscopic ... -
Molecular structure and computational studies on 2-((2-(4-(3-(2,5-dimethylphenyl)-3-methylcyclobutyl)thiazol-2-yl)hydrazono)methyl) phenol monomer and dimer by DFT calculations
Karakurt, Tuncay; Çukurovalı, Alaaddin; Subaşı, Nuriye Tuna; Kani, İbrahim (Elsevier Science BV, 2016)The title compound, 2-((2-(4-(3-(2,5-Dimethylphenyl)-3-methylcyclobutyl)thiazol-2-yl)hydrazono) methyl)phenol, was characterized by single-crystal X-ray diffraction. In order to calculate molecular geometry along with the ... -
N,N,N ',N '-Tetrakis(2-hydroxyethyl)ethylenediamine palladium(II) complex as efficient catalyst for the Suzuki/Miyaura reaction in water
Gülcemal, Süleyman; Kani, İbrahim; Yılmaz, Filiz; Çetinkaya, Bekir (Pergamon-Elsevier Science LTD, 2010)A new water soluble palladium(II) complex (2) derived from N,N,N',N'-tetrakis(2-hydroxyethyl)ethylenediamine (edteH(4)) (1) was synthesized in high yield and characterized by (1)H, (13)C, HMQC and COSY NMR spectroscopy. ... -
A New Application Area for Ag-NHCs: CO2 Fixation Catalyst
Taşçı, Zeynep; Kunduracıoğlu, Ahmet; Kani, İbrahim; Çetinkaya, Bekir (Wiley-V C H Verlag GMBH, 2012)The first example of the silver-NHC catalyzed cycloaddition of CO2 to terminal epoxides is reported. The choice of NHC substituents, halides and the nature of additives were determined to be important. Ionic [(Cnmim)2Ag]2[Ag2Br4] ... -
(NHC)-Pd(II) complexes with hydrophilic nitrogen ligands: catalytic properties in neat water
Türkmen, Hayati; Gök, Lütfiye; Kani, İbrahim (2013)The cleavage reactions of the dimers [(NHC)PdX2 ] 2 with hydrophilic N-donors, L, a?orded the mixedligand complexes of the type trans-[(NHC)LPdX2 ] (X = Cl or Br; NHC = 1,3-dialkylbenzimidazol-2-ylidene (BIm) or ... -
(NHC)-Pd(II) complexes with hydrophilic Nitrogen ligands; catalytic properties in neat water
Türkmen, Hayati; Gök, Lütfiye; Kani, İbrahim; Çetinkaya, Bekir (Scientific Technical Research Council Turkey-Tubitak, 2013)The cleavage reactions of the dimers [(NHC)PdX2](2) with hydrophilic N-donors, L, a ff orded the mixedligand complexes of the type trans-[(NHC)LPdX2] (X = Cl or Br; NHC = 1,3-dialkylbenzimidazol-2-ylidene (BIm) or bis(imino) ... -
A novel [Mn-2(mu-(C6H5)(2)CHCOO)(2)(bipy)(4)](bipy)(ClO4)(2) complex loaded solid lipid nanoparticles: synthesis, characterization and in vitro cytotoxicity on MCF-7 breast cancer cells
Eskiler, G. Güney; Cecener, G.; Dikmen, G.; Kani, İbrahim; Egeli, U.; Tunca, B. (Taylor & Francis LTD, 2016)Manganese (Mn)-based complexes have been drawing attention due to the fact that they are more effective than other metal complexes. However, the use of Mn(II)-based complexes in medicine remains limited because of certain ... -
Novel heteroleptic lanthanide organic frameworks containing pyridine-2,5-dicarboxylic acid and in situ generated piperazine-2,5-dicarboxylic acid from piperazine: Hydrothermal synthesis and luminescent properties
Ay, Burak; Yıldız, Emel; Kani, İbrahim (Academic Press Inc Elsevier Science, 2016)Two novel 3D lanthanide metal-organic frameworks [Ln(pydc)(pip)(1/2)(H2O] (Ln=Ce (1) and Pr (2), H(2)pydc=2,5-pyridinedicarboxylic acid, H(2)pip=2,5-piperazinedicarboxylic acid have been synthesized under hydrothermal ... -
A novel three dimensional samarium(III) coordination polymer with an unprecedented coordination mode of the 2,5-pyridinedicarboxylic acid ligand: Hydrothermal synthesis, crystal structure and luminescence property
Ay, Burak; Doğan, Nurhayat; Yıldız, Emel; Kani, İbrahim (Pergamon-Elsevier Science LTD, 2015)A novel three dimensional (3D) coordination polymer [Sm(pic)(2)(pydc)(4)(H2O)](n) (pydc = pyridine-2,5-dicarboxylate, Hpic = picolinic acid) (1) has been synthesized hydrothermally and characterized by elemental analysis, ... -
Oxygen bridged Homobinuclear Mn(II) compounds with Anthranilic acid: Theoretical calculations, oxidation and catalase activity
Su, Esra; Güven, Alaattin; Kani, İbrahim (Wiley, 2018)Two new homobinuclear manganese compounds with mixed ligands, [Mn-2((1,1)-2-NH2C6H4COO)(2)(phen)(4)](ClO4)2(CH3OH) (1), and [Mn-2((1,3)-2-NH2C6H4COO)(2)(bipy)(4)](ClO4)2 (2) (NH2C6H4COOH=anthranilic acid, bipy=2,2-bipyridine, ... -
Ruthenium(II) complexes bearing pyridine-based tridentate and bidentate ligands: catalytic activity for transfer hydrogenation of aryl ketones
Dayan, Osman; Dayan, Serkan; Kani, İbrahim; Çetinkaya, Bekir (Wiley, 2012)Ru(II) complexes of the general formula [RuCl2('NNN??')(L)] (1: 'N?=?Nb, L?=?MeOH; 2: 'N?=?Nb, L?=?CH3CN; 3: 'N?=?Nd, L?=?CH3CN; 4: 'N?=?Np, L?=?CH3CN), [Ru(p-cymene)(NN?ab)Cl]Cl (5a: N?Na?=?2,2'-bipyridine; 5b: ... -
Selective catalytic oxidation of alkenes employing homobinuclear manganese(II) catalysts with TBHP
Kılıç, Yalçın; Kani, İbrahim (Pergamon-Elsevier Science LTD, 2018)The two novel homobinuclear compounds [Mn-2((II,II)) (mu(1,1)-4-CH3-C6H4COO)(2)(phen)(4)](ClO4)(2) (1) and [Mn-2((II,II)) (mu(1,3)-4-CH3-C6H4COO)(2)(bipy)(4)](ClO4)(2) (2), where bipy=2,2-bipyridine and phen=1,10-phenanthroline, ... -
Semiconducting lanthanide polymers of pyridine-2,6-dicarboxylate: Hydrothermal synthesis, structural characterization, electrical conductivity and luminescence properties
Ay, Burak; Yıldız, Emel; Kani, İbrahim (Pergamon-Elsevier Science LTD, 2018)This paper describes the hydrothermal synthesis of two novel lanthanide coordination polymers (CPs) (H(2)piP)(n)[Ln(2)(PYdc)(4)(H2O)(2)](n) (Ln = La (1) and Nd (2), H(2)pydc = 2,6-pyridinedicarboxylic acid, H(2)pip = ... -
Spectroscopic (FT-IR, Laser-Raman and NMR) and conformational analysis on novel pyrazole beta-keto ester compound
Gümüş, Mehmet; Sert, Yusuf; Özdemir, Şahin; Gökçe, Halil; Kani, İbrahim; Koca, İrfan (Elsevier Science BV, 2018)Our goal in this study is to submit a comprehensive theoretical study of novel compound. Therefore, we perused and analyzed the experimental (real form) and theoretical (gas form) vibrational frequencies for the most stable ... -
Spectroscopic investigation of 2-(4-benzoyl-1,5-diphenyl-1H- pyrazol-3-yl)-4H-naphto[2,3-d][1,3] oxazin-4-one molecule
Sert, Yusuf; Gümüş, Mehmet; Kamaci, Volkan; Gökçe, Halil; Kani, İbrahim; Koca, İrfan (World Scientific Publ Co Pte LTD, 2017)In this present study, the experimental and theoretical vibrational frequencies of an important pharmacological molecule 2-(4-benzoyl-1,5-diphenyl-1H-pyrazol-3-yl)-4H-naphto[2,3-d][1,3] oxazin-4-one have been researched. ... -
Synthesis and catalytic activity of perfluoroalkylated pyridine-palladium(II) complex toward olefin hydrogenation in scCO(2) and conventional organic solvents
Kani, İbrahim; Şişman, Filiz (Elsevier Science BV, 2006)The perfluoroalkylated pyridine, (o-COOCH2(CF2)7CF(3)-NC5H4), has been synthesized in two step from nicotinic acid and then the title compound, [Pd(o-COOCH2,-(CF2)(7)CF3-NC5H4)(2)(OAc)(2)], obtained by reaction with ... -
Synthesis and characterization of a novel 3-amino-1,2,4-triazole lead(II) coordination polymer
Sözerli, Şebnem Esen; Özen, Arzu; Kani, İbrahim; Demir, Deniz (Scientific Technical Research Council Turkey-Tubitak, 2014)A novel [Pb-2(mu-atrz)(2)(mu-CH3COO)(CH3COO)](n) (atrz = 3 amino-1,2,4-triazole) complex was synthesized and characterized by IR spectroscopy, thermogravimetric analysis, and single crystal X-ray diffraction. The molecular ... -
Synthesis and characterization of peripheral and non-peripheral substituted Co(II) phthalocyanines and their catalytic activity in styrene oxidation
Saka, Ece Tuğba; Acar, İrfan; Bıyıklıoğlu, Zekeriya; Kantekin, Halit; Kani, İbrahim (Elsevier Science Sa, 2013)The synthesis of symmetrical cobalt(II) phthalocyanine complexes containing 2,2,3,3-tetrafluoro-1-propanoxy and 4-{2-[2-(1-naphthyloxy)ethoxy]ethoxy} groups obtained from 4-nitrophthalonitrile and 3-nitrophthalonitrile are ... -
Synthesis of an F-BODIPY [2]catenane using the chemistry of bis(dipyrrinato) metal complexes
Nisanci, Bilal; Şahinoğlu, Sinem; Tuner, Esra; Arık, Mustafa; Kani, İbrahim; Dastan, Arif; Bozdemir, Özgür Altan (Royal Soc Chemistry, 2017)ML2 type complexes of an olefin terminated 5H-dipyrrin ligand can be subjected to twofold ring closing metathesis to give bis(dipyrrinato)copper(II) and bis(dipyrrinato) zinc(II) [2] catenates. Demetalation of the copper(II) ... -
Synthesis, characterization and catalytic activity of novel Co(II) and Pd(II)-perfluoroalkylphthalocyanine in fluorous biphasic system; benzyl alcohol oxidation
özer, Metin; Yılmaz, Filiz; Erer, Hakan; Kani, İbrahim; Bekaroğlu, özer (Wiley, 2009)Tetra kis[heptadecafluorononyl] substituted phthalocyanine complexes were prepared by template synthesis from 4-(heptadecafluorononyloxy)phthalonitrile with Co(CH3COO)(2)center dot 4H(2)O or PdCl2 in 2-N,N-dimethylaminoethanol. ...