Yazar "Kani, İbrahim" için Fen Fakültesi listeleme
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1-Pentamethylbenzyl-3-(n)buthylbenzimidazolesilver(I)bromide complex: Synthesis, characterization and DFT calculations
Kunduracıoğlu, Ahmet; Tamer, Ömer; Avcı, Davut; Kani, İbrahim; Atalay, Yusuf; Çetinkaya, Bekir (Pergamon-Elsevier Science LTD, 2014)A novel NHC complex of silver(I) ion, 1-pentamethylbenzyl-3-(n)buthylbenzimidazolesilver(I)bromide, was prepared and fully characterized by single crystal X-ray structure determination. FT-IR, NMR and UV-vis spectroscopies ... -
The Anticancer Activity of Complex [Cu-2(mu-(C6H5)(2)CHCOO)(3)(bipy)(2))](ClO4) -Solid Lipid Nanoparticles on MCF-7 Cells
Kani, İbrahim; Dikmen, Gökhan; Eskiler, Gamze Güney; Cecener, gülsah; Tunca, Berrin; Egeli, Ünal (Bentham Science Publ LTD, 2016)Recent studies have focused on the potential use of metal-based complexes for the treatment of cancer. However, there are some limitations of metal-based ligands for the treatment of cancer due to their toxic effects. In ... -
A carboxylate-bridged Mn(II) compound with 6-methylanthranilate/bipy: oxidation of alcohols/alkenes and catalase-like activity
Kılıç, Yalçın; Bolat, Serkan; Kani, İbrahim (Taylor & Francis LTD, 2018)A novel manganese compound, [Mn-2((1,3)-6-CH3-2-NH2C6H4COO)(2)(bipy)(4)](ClO4)(2) (bipy=2,2-bipyridine), was synthesized and used as a catalyst precursor in the oxidation of alkenes and primary alcohols to corresponding ... -
Catalytic Activity of a Thermoregulated, Phase-Separable Pd(II)-perfluoroalkylphthalocyanine Complex in an Organic/Fluorous Biphasic System: Hydrogenation of Olefins
Yılmaz, Filiz; Özer, Metin; Kani, İbrahim; Bekaroğlu, özer (Springer, 2009)A fluoroalkene-soluble tetrakis[heptadecafluorononyl]-substituted Pd(II)-phthalocyanine complex has been studied for olefin (styrene, 1-octene, trans-2-octene and cyclohexene) hydrogenation with molecular hydrogen in an ... -
Crystal structure of an unsymmetrical Schiff base, immobilization of its cobalt and manganese complexes on a silica support, and catalytic studies
Durak, Damla; Delikanli, Anıl; Demetgül, Cahit; Kani, İbrahim; Serin, Selahattin (Springer, 2013)An unsymmetrical tetradentate Schiff base (H2L) was synthesized by the reaction of 3-methoxysalicylaldehyde, o-phenylenediamine, and salicylaldehyde in EtOH. H2L was characterized by single-crystallographic X-ray analysis. ... -
Crystal structure of aquabis(heptafluorobutanoato-kappa O)(1,10 '-phenanthroline-kappa N-2,N ')copper(II)
Kani, İbrahim (Int Union Crystallography, 2016)The title compound, [Cu(C4F7O2)(2)(C12H8N2)(H2O)], is mononuclear and contains a pentacoordinated Cu-II ion. The geometry of Cu-II ion can be described as distorted square-pyramidal with two O atoms of two butanoate anions ... -
Crystal structure of bis(mu-2-benzoylbenzoato-kappa O-2:O')bis[bis(2,2'-bipyridine-kappa N-2,N')manganese(II)] bis(perchlorate)
Kani, İbrahim (Int Union Crystallography, 2015)The title compound, [Mn-2(C6H5COC6H4COO)(2)(C10H8N2)(4)](ClO4)(2), comprises a centrosymmetric binuclear cation and two perchlorate anions. In the complex cation, two Mn-II atoms are bridged by two 0 atoms of two different ... -
Effective catalytic oxidation of alcohols and alkenes with monomeric versus dimeric manganese(II) catalysts and t-BuOOH
Kani, İbrahim; Bolat, Serkan (Wiley, 2016)Two new Mn(II) complexes, [Mn(C6H5COO)(H2O)(phen)(2)](ClO4)(CH3OH) (1) and [Mn-2(-C6H5COO)(2)(bipy)(4)]2(ClO4) (2) (phen = 1,10-phenanthroline; bipy = 2,2-bipyridine), were synthesized and characterized using UV-visible ... -
Evaluation of polymer-supported rhodium catalysts in 1-octene hydroformylation in supercritical carbon dioxide
Lopez-Castillo, Z. K.; Flores, R.; Kani, İbrahim; Fackler, Jr., J. P.; Akgerman, A. (American Chemical Society, 2003)Supercritical CO2 has been used as a benign solvent in the hydroformylation of 1-octene using a Rh-based catalyst. The catalyst is attached to a polymer backbone that has fluoroacrylate branches that make it soluble in ... -
Experimental and theoretical studies on tautomeric structures of a newly synthesized 2,2'(hydrazine-1,2-diylidenebis(propan-1-yl-1-ylidene)) diphenol
Karakurt, Tuncay; Çukurovalı, Alaaddin; Subaşı, Nuriye Tuna; Onaran, Abdurrahman; Ece, Abdulilah; Eker, Sıtkı; Kani, İbrahim (Elsevier Science BV, 2018)In the present study, a single crystal of a Schiff base, 2,2'(hydrazine-1,2-diylidenebis(propan-1-yl-1-ylidene)) diphenol, was synthesized. The structure of the synthesized crystal was confirmed by H-1 and C-13 NMR ... -
A facile protocol for the preparation of 5-alkylidene and 5-imino substituted hydantoins from N,N '-disubstituted parabanic acids
Üngören, Sevket Hakan; Kani, İbrahim; Günay, Ahmet (Pergamon-Elsevier Science LTD, 2012)A convenient procedure for the preparation of various substituted (thio)hydantoins is described. The method is based on Wittig and aza-Wittig reactions of parabanic acids with phosphonium ylides. The reactions occurred ... -
HETEROGENIZATION OF HOMOGENEOUS PERFLUOROTHIOPHENE Rh(I) COMPLEX AND EXAMINATION OF HYDROGENATION ACTIVITY IN scCO2 MEDIA
Yılmaz, Filiz; Karaağaç, Yusuf; Kani, İbrahim (2018)Rhodium(I) complex of perfluorinated thiophene ligand was synthesized and heterogenized over the modified silica support. SEM, XRF, TGA and BET methods were used for the characterization of the heterogenized catalyst ... -
Homogeneous oxidation of alcohol and alkene with copper (II) complex in water
Ünver, Hakan; Kani, İbrahim (Indian Acad Sciences, 2018)A new water-soluble copper(II) complex bearing 4-bromobenzoate/ 2,2'-dipyridylamine ligands was successfully synthesized and characterized by using single crystal X-ray diffraction and spectroscopic techniques. The catalytic ... -
Homogeneous oxidation of alcohols in water catalyzed by a Cu(II) complex with a triphenyl acetate/ bipyridyl ligands
Ünver, Hakan; Kani, İbrahim (American Chemical Society, 2017)… -
Homogeneous oxidation of alcohols in water catalyzed with Cu(II)-triphenyl acetate/bipyridyl complex
Ünver, Hakan; Kani, İbrahim (Pergamon-Elsevier Science LTD, 2017)A water-soluble mononuclear copper(II) complex, [Cu(OOCC(C6H5)(3))(C10H8H2)(H2O)](ClO4)(CH3OH) (triphenylacetic acid = HOOCC(C6H5)(3), 2-2'-bipyridyl (bipy) = C10H8N2) was synthesized and used as a catalyst precursor in ... -
Hydrogen bonded networks and a self-assembled 1D water cluster in nickel(II) and copper(II)-orotate complexes
Yeşilel, Okan Zafer; Erer, Hakan; Kastas, Gökhan; Kani, İbrahim (Pergamon-Elsevier Science LTD, 2010)Three Ni(II) and Cu(II)-orotate complexes with 1,3-propanediamine (pen) and N-methylethylenediamine (nmen), [Ni(HOr)(H(2)O)(2)(pen)] (1), [Cu(2)(mu-HOr)(2)(pen)(2)] (2) and {[Cu(mu-HOr)(nmen)]center dot 3H(2)O}(n) (3) ... -
Hydrogenation of olefins catalyzed by Pd(II) complexes containing a perfluoroalkylated S,O-chelating ligand in supercritical CO2 and organic solvents
Yılmaz, Filiz; Mutlu, Aylin; Ünver, Hakan; Kurtca, Mehmet; Kani, İbrahim (Elsevier Science BV, 2010)Pd(II) complexes with the tridentate ligands heptadecafluorodecyl-thiophene-2-carboxylate (L-1 = SOSRf1, R-f1 = (CH2)(2)(CF2)(7)CF3) and heptadecafluorononil thiophene-2-carboxylate (L-2 = SOORf2, R-f2 =(CH2)(CF2)(7)CF3) ... -
Hydrothermal Synthesis and Crystal Structures of Cd(II)-Based 1D Coordination Polymer and Mn(II) Coordination Complex with Mixed N- and O-donor Ligands: [Cd-2(4-4'-bpy)(2)(pa)(4)] (n) center dot 0.25(H2O) and [Mn(4-4'-bpy)(2)(pa)(H2O)(3)]ClO4 center dot 2(H2O)
Kani, İbrahim; Aksu, Yılmaz (Springer, 2010)Two new complexes, [Cd-2(4-4'-bpy)(2)(pa)(4)] (n) center dot 0.25H(2)O (1) (pa = phenylacetate), and [Mn(4-4'-bpy)(2)(pa)(H2O)(3)]ClO4 center dot 2H(2)O, (2), have been obtained from hydrothermal reaction of Cd(NO3)(2)center ... -
Mn(II) complexes with bipyridine, phenanthroline and benzoic acid: Biological and catalase-like activity
Kani, İbrahim; Atlier, Özlem; Güven, Kıymet (Indian Acad Sciences, 2016)Five mononuclear Mn(II) complexes, [Mn(phen)(2)(ClO4)(2)] (1), [Mn(phen)(3)](ClO4)(2)(H2CO3)(2)(2), [Mn(bipy)(2)(ClO4)(2)] (3), [Mn(bipy)(3)](ClO4)(2)) (4), and Mn(phen)(2)(ba)(H2O)](ClO4)(CH3OH) (5), where bipy = ...