dc.contributor.author | Özsin, Gamzenur | |
dc.contributor.author | Pütün, Ayşe Eren | |
dc.date.accessioned | 2019-10-21T21:11:54Z | |
dc.date.available | 2019-10-21T21:11:54Z | |
dc.date.issued | 2017 | |
dc.identifier.issn | 0196-8904 | |
dc.identifier.issn | 1879-2227 | |
dc.identifier.uri | https://dx.doi.org/10.1016/j.enconman.2017.07.059 | |
dc.identifier.uri | https://hdl.handle.net/11421/21209 | |
dc.description | WOS: 000411537200056 | en_US |
dc.description.abstract | The purpose of this study was to investigate the effect on polystyrene (PS) during co-pyrolysis with biomass through thermal decomposition. The model-free iso-conversional methods (Kissinger, Friedman, Flynn-WallOzawa, Kissinger-Akahira-Sunose, Starink and Vyazovkin) were adopted to calculate activation energy of the pyrolysis and co-pyrolysis process of two biomass samples (walnut shell: WS and peach stones: PST) with PS. It is found that biomass blending to PS decreased activation energy values and resulted in multi-step reaction mechanisms. Furthermore, changes in the evolution profiles of methyl, water, methoxy, carbon dioxide, benzene and styrene was monitored through evolved gas analysis via TGA/FT-IR and TGA/MS. Detection of temperature dependent release of volatiles indicated the differences occur as a result of compositional differences of biomass. | en_US |
dc.description.sponsorship | TUBITAK through the BIDEB 2214-A | en_US |
dc.description.sponsorship | The authors would like to acknowledge the financial support of TUBITAK through the BIDEB 2214-A to foster international collaborations for further complementary research. | en_US |
dc.language.iso | eng | en_US |
dc.publisher | Pergamon-Elsevier Science LTD | en_US |
dc.relation.isversionof | 10.1016/j.enconman.2017.07.059 | en_US |
dc.rights | info:eu-repo/semantics/closedAccess | en_US |
dc.subject | Biomass | en_US |
dc.subject | Polystyrene | en_US |
dc.subject | Pyrolysis | en_US |
dc.subject | Tga/Ms/Ft-Ir | en_US |
dc.subject | Kinetic | en_US |
dc.subject | Gas Analysis | en_US |
dc.title | Insights into pyrolysis and co-pyrolysis of biomass and polystyrene: Thermochemical behaviors, kinetics and evolved gas analysis | en_US |
dc.type | article | en_US |
dc.relation.journal | Energy Conversion and Management | en_US |
dc.contributor.department | Anadolu Üniversitesi, Mühendislik Fakültesi, Kimya Mühendisliği Bölümü | en_US |
dc.identifier.volume | 149 | en_US |
dc.identifier.startpage | 675 | en_US |
dc.identifier.endpage | 685 | en_US |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |