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dc.contributor.authorÖzsin, Gamzenur
dc.contributor.authorPütün, Ayşe Eren
dc.date.accessioned2019-10-21T21:11:54Z
dc.date.available2019-10-21T21:11:54Z
dc.date.issued2017
dc.identifier.issn0196-8904
dc.identifier.issn1879-2227
dc.identifier.urihttps://dx.doi.org/10.1016/j.enconman.2017.07.059
dc.identifier.urihttps://hdl.handle.net/11421/21209
dc.descriptionWOS: 000411537200056en_US
dc.description.abstractThe purpose of this study was to investigate the effect on polystyrene (PS) during co-pyrolysis with biomass through thermal decomposition. The model-free iso-conversional methods (Kissinger, Friedman, Flynn-WallOzawa, Kissinger-Akahira-Sunose, Starink and Vyazovkin) were adopted to calculate activation energy of the pyrolysis and co-pyrolysis process of two biomass samples (walnut shell: WS and peach stones: PST) with PS. It is found that biomass blending to PS decreased activation energy values and resulted in multi-step reaction mechanisms. Furthermore, changes in the evolution profiles of methyl, water, methoxy, carbon dioxide, benzene and styrene was monitored through evolved gas analysis via TGA/FT-IR and TGA/MS. Detection of temperature dependent release of volatiles indicated the differences occur as a result of compositional differences of biomass.en_US
dc.description.sponsorshipTUBITAK through the BIDEB 2214-Aen_US
dc.description.sponsorshipThe authors would like to acknowledge the financial support of TUBITAK through the BIDEB 2214-A to foster international collaborations for further complementary research.en_US
dc.language.isoengen_US
dc.publisherPergamon-Elsevier Science LTDen_US
dc.relation.isversionof10.1016/j.enconman.2017.07.059en_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectBiomassen_US
dc.subjectPolystyreneen_US
dc.subjectPyrolysisen_US
dc.subjectTga/Ms/Ft-Iren_US
dc.subjectKineticen_US
dc.subjectGas Analysisen_US
dc.titleInsights into pyrolysis and co-pyrolysis of biomass and polystyrene: Thermochemical behaviors, kinetics and evolved gas analysisen_US
dc.typearticleen_US
dc.relation.journalEnergy Conversion and Managementen_US
dc.contributor.departmentAnadolu Üniversitesi, Mühendislik Fakültesi, Kimya Mühendisliği Bölümüen_US
dc.identifier.volume149en_US
dc.identifier.startpage675en_US
dc.identifier.endpage685en_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US


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